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Acids, Bases and Salts.
Classification of matter
On the basis of
a) composition - elements, compounds and mixtures
b) state-solids, liquids and gases
c) solubility - suspensions, colloids and solutions
Types of mixtures - homogeneous and heterogeneous
Types of compounds- covalent and ionic
lonisable and non-ionisable compounds
An ionisable compound when dissolved in water or in its molten state,
dissociates into ions almost entirely. Example: NaCl, HCI, KOH, etc. A non-lonisable compound does not dissociate into ions when dissolved in
water or in its molten state. Example: glucose, acetone, etc.
Arrhenius theory of acids and bases
Arrhenius acid when dissolved in water, dissociates to give H" (aq) or H0 ion Arrhenius base - when dissolved in water; dissociates to give OH ion.
Examples:
Acids
Hydrochloric acid (HCI)
Sulphuric acid (H₂50₁)
Nitric acid (HNO₂)
Bases
Sodium hydroxide (NaOH)
Potassium hydroxide (KOH)
Calcium hydroxide (Ca(OH):)
Bronsted Lowry theory
A Bronsted and is a H(aq) londonor.
A Bronsted base is a H(aq) ion acceptor.
Example
In the reaction: HCl(aq) + NH₂(aq) + NH(aq) + Cl(aq)
MCI - Bronsted acid and C-its conjugate acid
NH,- Bronsted base and NH₂ - its conjugate acid
Physical test.
Given are two possible physical tests to identify an acid or a base.
a. Taste
An acid tastes sour whereas a base tastes bitter. The method of taste is not advised as an acid or a base could be contaminated or corrosive
b. Effect on indicators by acids and bases
An indicator is a chemical substance which shows a change in its physical properties, mainly colour or odour when brought in contact with an acid or a base.
Below mentioned are commonly used indicators and the different colours
they exhibit:
a) Litmus
In neutral solution - purple
In acidic solution - red
In basic solution - blue
Litmus is also available as strips of paper in two variants - red litmus and blue litmus.
An acid turns a moist blue litmus paper to red. A base turns a moist red litmus paper to blue
b) Methyl orange
In neutral solution - orange
In acidic solution - red
In basic solution-yellow